全文获取类型
收费全文 | 551篇 |
免费 | 36篇 |
国内免费 | 4篇 |
专业分类
化学 | 372篇 |
力学 | 10篇 |
数学 | 52篇 |
物理学 | 157篇 |
出版年
2023年 | 3篇 |
2022年 | 8篇 |
2021年 | 26篇 |
2020年 | 23篇 |
2019年 | 27篇 |
2018年 | 23篇 |
2017年 | 14篇 |
2016年 | 28篇 |
2015年 | 26篇 |
2014年 | 26篇 |
2013年 | 48篇 |
2012年 | 39篇 |
2011年 | 53篇 |
2010年 | 35篇 |
2009年 | 32篇 |
2008年 | 41篇 |
2007年 | 23篇 |
2006年 | 14篇 |
2005年 | 17篇 |
2004年 | 17篇 |
2003年 | 11篇 |
2002年 | 18篇 |
2001年 | 3篇 |
2000年 | 6篇 |
1999年 | 4篇 |
1998年 | 4篇 |
1997年 | 2篇 |
1996年 | 4篇 |
1995年 | 1篇 |
1994年 | 1篇 |
1992年 | 3篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1985年 | 1篇 |
1983年 | 2篇 |
1981年 | 3篇 |
1979年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有591条查询结果,搜索用时 15 毫秒
41.
Mehmet Atilla Tasdelen Selim Beyazit Deniz Gunes Niyazi Bicak Pinar Tatar A. Levent Demirel Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》2011,49(18):4021-4026
The synthesis of poly(p‐phenylene methylene) (PPM)‐based block copolymers such as poly(p‐phenylene methylene)‐b‐poly(ε‐caprolactone) and poly(p‐phenylene methylene)‐b‐polytetrahydrofuran by mechanistic transformation was described. First, precursor PPM was synthesized by acid‐catalyzed polymerization of tribenzylborate at 16 °C. Then, this polymer was used as macroinitiators in either ring‐opening polymerization of ε‐caprolactone or cationic ring‐opening polymerization of tetrahydrofuran to yield respective block copolymers. The structures of the prepolymer and block copolymers were characterized by GPC and 1H NMR investigations. The composition of block copolymers as determined by 1H NMR and TGA analysis was found to be in very good agreement. The thermal behavior and surface morphology of the copolymers were also investigated, respectively, by differential scanning calorimetry and atomic force microscopy measurements, and the contribution of the major soft segment has been observed. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
42.
Cagatay Altinkok Baris Kiskan Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》2011,49(11):2445-2450
The preparation of soluble and processable polybenzoxazine precursors capable of forming high performance networks is an important field of research with a broad spectrum of application. This study demonstrates an approach that utilizes aromatic sulfonediamine, bisphenol‐A, and formaldehyde in Mannich‐type polycondesation to prepare polybenzoxazine precursor. The structure of the oligomeric precursor (Mn = 2600) was confirmed by FTIR and 1H NMR spectral analysis. The precursor contained both sulfone and benzoxazine ring structures in the backbone. It was shown that small amount of ring‐opened phenolic groups were also present. Thermally activated self‐curing behavior of precursor in the absence of catalyst was studied by differential scanning calorimetry. Thermal properties of the cured polymers were also investigated by thermo gravimetric analysis. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
43.
Tijen Tanyalcin Diler Aslan Yusuf Kurtulmus Nalan Gökalp Kamil Kumanlioğlu 《Accreditation and quality assurance》2000,5(9):383-387
In this study the reference intervals for folate and vitamin B12 were estimated according to the National Committee for Clinical Laboratory Standards Approved Guideline C28-A and International
Federation of Clinical Chemistry recommendations. The study included 155 women and 124 men between ages 18–40. The health
status was confirmed by history, physical examination and a questionnaire. The central 95% reference intervals of serum folate
and vitamin B12 for women, determined non-parametrically, were found to be 3.9–18.1 ng/ml and 101–666.7 pg/ml, respectively.
The reference values of serum folate and vitamin B12 for men were also found to be 2,5–17.6 ng/ml and 100–699.57 pg/ml, respectively.
We did not observe subclass differences between females and males.
Received: 15 April 2000 · Accepted: 15 April 2000 相似文献
44.
Yusuf Kurtulmus T. Tanyalçın Giray Bozkaya Ogˇuzhan Gündüz Ömür Çerçi Fatma Z. Kutay Biltan Ersöz 《Accreditation and quality assurance》2001,6(9-10):424-426
The aim of this study was to compare two immunoassay measurement methods, the ACS:180 Plus (Chiron Diagnostics) kit and the Immulite sPSA (DPC) kit. Method comparison analysis was performed according to EP9-A; approved guideline of NCCLS 51. Serum samples having a wide range of total prostate-specific antigen (PSA) concentrations were evaluated in split-sample analysis. F-test, t-test analysis and regression statistics were performed. In Deming regression analysis the coefficients were as follows; the slope=0.967; y-intercept=-0.148, r=0.989. An acceptable bias was seen since the systematical error was calculated to have a value less than the total allowable error calculated from biological variations. Non-parametric evaluation of the area under ROC curves for ACS:180 Plus and Immulite sPSA were 0.997 and 0.987, respectively. Diagnostic accuracy was at the level of p= 0.000 and no statistical difference was found between the two assay methods. 相似文献
45.
Niyazi Bicak Umit Tunca Yusuf Yagci 《Journal of polymer science. Part A, Polymer chemistry》1989,27(11):3759-3767
Three new polyamidoximes (PAO) having appropriate functionalities to bind transition metal ions were prepared. The polymers were obtained by the reaction of dichlorooximino ethane with the corresponding diamine. Characterization and crosslinking of PAOs via coordination with transition metal ions such as Ni(II), Co(II), Cu(II), and UO2(II) are presented. The crosslinked polymer complexes exhibit good thermal stability. It was also found that both square planar and tetrahedral coordination structures are present in the crosslinked polymers. 相似文献
46.
We calculate the energy eigenvalues and the sate functions of one-electron Quantum Dot (QD) by using a combination of Quantum Genetic Algorithm (QGA) and Hartre-Fock-Roothaan (HFR) method. The linear and the third-order nonlinear optical absorption coefficients for the 1s-1p, 1p-1d, and 1d-1f transitions are examined as a function of the incident photon energy for three different values of the stoichiometric ratio. The results show that the stoichiometric ratio, impurity, relaxation time, and dot size have great influence on the optical absorption coefficients of QDs. 相似文献
47.
Avcı Davut Altürk Sümeyye Sönmez Fatih Tamer Ömer Başoğlu Adil Atalay Yusuf Zengin Kurt Belma Dege Necmi 《Molecular diversity》2021,25(1):171-189
Molecular Diversity - The World Health Organization (WHO) report shows that diabetes mellitus (DM) will be one of the ten deadly diseases in the near future. The best way to prevent DM is to... 相似文献
48.
Emel Yildiz Sadet Karabulut Neslihan S. Pinar Yusuf Karatas Figen Doran 《无机化学学报》2010,26(10):1743-1749
3,3,4,7-四羟基黄酮与1,3-二环己基碳二亚胺在4-二甲胺吡啶存在下反应,得到2,2-双(3,3,4,7-四羟基黄酮)1,3-二环己基碳二亚胺。三价金属离子与上述合成得到的配体螯合,对此四面体结构的双核Fe(Ⅲ)配合物的血液学及病理学数据进行了讨论,同时研究了合成的配体作为螯合剂清除鼠肝胰组织中超载的铁的能力。结果表明作为口服药其作为双齿配体的螯合能力与市售用于治疗地中海贫血的药物"去铁敏"相近。 相似文献
49.
A. Ali Yusuf A.K. Yahya Nawazish A. Khan F. Md. Salleh E. Marsom N. Huda 《Physica C: Superconductivity and its Applications》2011,471(11-12):363-372
Substitution of Ge4+ in place of Cu in Tl0.85Cr0.15Sr2CaCu2?xGexO7?δ (x = 0–0.6) showed initial increase in zero critical temperature value, Tc zero from 98 K (x = 0) to 100 K (x = 0.1) and in the range of 85–86 K for x = 0.2–0.3. The slow decrease in Tc zero is unexpected as tetravalent Ge4+ substitution is expected to strongly reduce hole concentration in the samples and suppress Tc zero. Excess conductivity analyses of resistance versus temperature data based on Asmalazov–Larkin (AL) theory revealed that the substitution induced 2D-to-3D transition of fluctuation induced conductivity with the highest transition temperature, T2D–3D observed at x = 0.1. FTIR spectroscopy analysis indicates Ge4+ substitution cause reduction in CuO2/GeO2 interplanar distance while our calculation based on Lawrence–Doniach model revealed highest superconducting coherence length, ξc(0) and interplanar coupling, J at x = 0.3. On the other hand, substitution of divalent Mg2+ for Ca2+ in (Tl0.5Pb0.5)(Sr1.8Yb0.2)(Ca1?yMgy)Cu2O7 (y = 0–1.0), which is not expected to directly vary hole concentration, surprisingly caused Tc zero to increase from 89.6 K (y = 0) to an optimum value of 95.9 K (y = 0.6) before decreasing with further increase in y. Excess conductivity analyses showed 2D-to-3D transition of fluctuation induced conductivity for all samples where the highest T2D–3D was at y = 0.4. Similar calculation revealed highest values of ξc(0) and J also at y = 0.4. FTIR analysis of the samples indicates inequivalent Cu(1)O(2)Pb/Tl lengths and possible tilting of CuO2 plane as a result of Mg2+ substitution. The increased ξc(0) and J as a result of the Ge4+ and Mg2+ substitutions are suggested to contributed to sustenance of superconductivity above 80 K in the samples. 相似文献
50.
The effect of electron doping on the magnetic properties of the brownmillerite type bilayered compounds has been investigated by neutron powder diffraction in La substituted Ca(2.5-x)La(x)Sr(0.5)GaMn(2)O(8) compounds (x = 0.05 and 0.1), in comparison with the undoped compound (x = 0). In all compounds, a long-range three-dimensional collinear antiferromagnetic (AFM) structure is found below the Néel temperature T(N) of the respective compound, whereas, well above T(N), three-dimensional short-range magnetic ordering is observed. In the intermediate temperature range just above T(N), a strong effect of electron doping (La substitution) on the magnetic correlations has been observed. Here, a short-range AFM correlation with a possible dimensionality of three has been found for substituted compounds (x = 0.05 and 0.1) as compared to the reported two-dimensional long-range AFM ordering in the parent compound. With increasing electron doping, a decrease in T(N) is also observed. The short-range magnetic correlations set in over a large temperature range above T(N). A magnetic phase diagram in the x-T plane is proposed from these results. 相似文献